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Metal Interactions with Boron Clusters - Russell N. Grimes

Metal Interactions with Boron Clusters

Buch | Hardcover
327 Seiten
1982
Kluwer Academic/Plenum Publishers (Verlag)
978-0-306-40933-2 (ISBN)
CHF 224,65 inkl. MwSt
Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif­ ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.

1. Structural and Bonding Features of Metallaboranes and Metallacarboranes.- 2. Transition-Metal Derivatives of Nido-Boranes and Some Related Species.- 3. Interactions of Metal Groups with the Octahydrotriborate (1?) Anion, B3H8?.- 4. Metallaboron Cage Compounds of the Main Group Metals.- 5. closo-Carborane-Metal Complexes Containing Metal-Carbon and Metal-Boron ?-Bonds.- 6. Electrochemistry of Metallaboron Cage Compounds.- 7. Boron Clusters with Transition Metal-Hydrogen Bonds.

Erscheint lt. Verlag 31.12.1982
Reihe/Serie Modern Inorganic Chemistry
Zusatzinfo XIV, 327 p.
Verlagsort New York
Sprache englisch
Maße 155 x 235 mm
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
ISBN-10 0-306-40933-X / 030640933X
ISBN-13 978-0-306-40933-2 / 9780306409332
Zustand Neuware
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