Key Structural Factors of Group 5 Metal Oxide Clusters for Base Catalytic Application

Shun Hayashi (Autor)

Buch | Hardcover

92 Seiten

2020 | 1st ed. 2020
Springer Verlag, Singapore
978-981-15-7347-7 (ISBN)

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This book provides detailed information on the base catalysis of group 5 (Nb, Ta) metal oxide clusters by elucidating how the structural factors such as constituent metals, counter cations, and local structures of base sites affect their catalysis. Uniquely, it reveals the effects of key structural factors at the molecular level by combining experimental and theoretical approaches. The findings presented here provide rational design principles for base catalysis and will foster the development of promising catalysts for solving current and future energy and environmental problems.

Shun Hayashi is a Postdoctoral Fellow at Tokyo Metropolitan University. His work mainly involves catalytic chemistry and cluster science. He received his Bachelor, Master and PhD in Science from the University of Tokyo in 2014, 2016 and 2019, respectively. He was awarded a research fellowship for young scientists from the Japan Society for the Promotion of Science (JSPS), and was supported by JSPS during his doctoral program.

1. General Introduction.- 2. Application of Group 5 Polyoxometalate as an Efficient Base Catalyst: a Case Study of [Nb10O28]6–.- 3. Effect of Counter Cation on the Base Catalytic Activity of [Nb10O28]6–.- 4. Lewis Base Catalytic Properties of [Nb10O28]6− for CO2 Fixation to Epoxide: Kinetic and Theoretical Studies.- 5. Superior Base Catalysis of Group 5 Hexametalates over Group 6 Hexametalates.- 6. Concluding Remarks.

Erscheinungsdatum	14.08.2020
Reihe/Serie	Springer Theses
Zusatzinfo	32 Illustrations, color; 53 Illustrations, black and white; XII, 92 p. 85 illus., 32 illus. in color.
Verlagsort	Singapore
Sprache	englisch
Maße	155 x 235 mm
Themenwelt	Naturwissenschaften ► Chemie ► Physikalische Chemie
Themenwelt	Technik ► Maschinenbau
Schlagworte	Base Catalyst • CO2 Fixation • Group 5 Element • Metal Oxide Cluster • polyoxometalate
ISBN-10	981-15-7347-6 / 9811573476
ISBN-13	978-981-15-7347-7 / 9789811573477
Zustand	Neuware