Recent Advances in Zeolite Science (eBook)

P.J. Barrie, J. Klinowski (Herausgeber)

eBook Download: PDF

1989 | 1. Auflage
308 Seiten
Elsevier Science (Verlag)
978-0-08-088745-6 (ISBN)

Infos

Interest in zeolites continues to grow, making it vital to keep up to date with recent findings. These proceedings include some of the latest discoveries in the zeolite field. Four plenary lectures provide in-depth coverage of key topics, namely the influence of diffusion on catalysis, recent advances in synthesis, modification of zeolites by alumination, and quantum chemical studies of acidity. These are followed by nineteen papers written by contributors from all over the world covering a wide range of material of current interest. Several synthetic studies are presented, including the introduction of heteroatoms to induce higher catalytic acidity. Acidity and catalysis are probed by solid-state NMR and discussed through theoretical calculations. Two papers are concerned with the growing interest in using zeolites to catalyze shape-selective organic reactions. There are specific studies of zeolite characterization by NMR and electron energy loss spectroscopy. There are also a number of quantum chemical papers on zeolite stability and on the location of adsorbed species.

The material presented is particularly up-to-date and will be of considerable interest to all research groups involved in zeolite sciences.

Inhalt

Front Cover 1
Recent Advances in Zeolite Science 4
Copyright Page 5
Contents 6
PART I: PLENARY LECTURES 10
Chapter 1. Influence of diffusion and adsorption of reactants on gas-solid catalytic reactions on zeolites 10
Chapter 2. Recent advances in zeolite synthesis 26
Chapter 3. Hydrothermal alumination of zeolites 48
Chapter 4. Quantum chemical studies of zeolite acidity 82
PART II: SUBMITTED PAPERS 100
Chapter 5. Solid-state NMR studies of shape selectivity in zeolites 100
Chapter 6. Isomorphous substitution in zeolite ZSM-5 122
Chapter 7. Zeolite catalysts modified with fluorine 132
Chapter 8. The effect of interacting molecules and cations on the properties of hydroxyl groups in zeolites: a quantum chemical study 142
Chapter 9. Selective synthesis of carbonyl compounds using zeolites 148
Chapter 10. 29Si MAS NMR of zeolites: semi-empirical interpretation of chemical shifts and their relation to structure parameters 160
Chapter 11. Zeolite-induced phagocytic free radicals and their potential relevance to the pathogenesis of Alzheimer’s Disease 172
Chapter 12. High resolution solid-state 1H NMR studies of zeolites 178
Chapter 13. 31P solid-state MAS NMR spectra: fingerprints of microporous aluminophosphates and silicoaluminophosphates 202
Chapter 14. Computer simulation studies of zeolite structure and stability 212
Chapter 15. Synthesis of SAPO-37 218
Chapter 16. The influence of history dependent factors on the properties of zeolite catalysts 224
Chapter 17. Localized electron energy loss spectroscopy of zeolite catalysts in the electron microscope 236
Chapter 18. Factorial design of the ammonia-based synthesis of large uniform MFI, MEL, DOH and DOH/DDR type zeolite crystals 250
Chapter 19. A Monte Carlo study of benzene and para-xylene in zeolite theta-1 262
Chapter 20. Modified metallosilicates: are they viable catalysts? 270
Chapter 21. Computer simulation of hydrocarbons in zeolites 280
Chapter 22. The formation of 2,6-lutidine from acetone, methanol and ammonia over zeolite ZSM-5 292
Chapter 23. NMR characterization of zeolite H-ZSM-5 after post-synthesis modification with H3PO4 304
List of contributors 314
Studies in Surface Science and Catalysis (other volumes in the series) 316

Produkt-Details

• Erscheint lt. Verlag: 28.11.1989
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Naturwissenschaften ► Geowissenschaften ► Mineralogie / Paläontologie
• Themenwelt: Technik ► Bauwesen
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• ISBN-10: 0-08-088745-7 / 0080887457
• ISBN-13: 978-0-08-088745-6 / 9780080887456