Molecular Soft-Interface Science (eBook)

Principles, Molecular Design, Characterization and Application

Hiromi Kitano, Mizuo Maeda, Yoshiko Miura, Atsushi Takahara, Tetsuji Yamaoka (Herausgeber)

eBook Download: PDF

2019 | 1st ed. 2019
VIII, 222 Seiten
Springer Japan (Verlag)
978-4-431-56877-3 (ISBN)

Infos

This book offers a comprehensive treatment of the molecular design, characterization, and physical chemistry of soft interfaces. At the same time, the book aims to encourage the fabrication of functional materials including biomaterials. During the past few decades there has been steady growth in soft-interface science, and that growth has been especially rapid in the twenty-first century. The field is interdisciplinary because it involves chemistry, polymer science, materials science, physical chemistry, and biology. Based on the increasing interdisciplinary nature of undergraduate and graduate programs, the primary goal of this present work is to serve as a comprehensive resource for senior-level undergraduates and for graduate students, particularly in polymer chemistry, materials science, bioconjugate chemistry, bioengineering, and biomaterials. Additionally, with the growing interest in the fabrication of functional soft materials, this book provides essential fundamental information for researchers not only in academia but also in industry.

Mizuo Maeda

Mizuo Maeda received his Ph.D. from the University of Tokyo (1983). He was a full professor of materials physics and chemistry at Kyushu University before moving to RIKEN Institute as a chief scientist and a director of Bioengineering Laboratory. His research interests center on polymer chemistry, analytical chemistry, and biomaterials science.

 

Atsushi Takahara

Atsushi Takahara earned his D.Eng. (1983) in the field of polymer science. Since 1999, he is a full professor of Kyushu University. His research interests are focused on advanced soft materials such as polymer ultrathin films, polymer nanocomposites, and novel tough polymers.  

 

Hiromi Kitano

Hiromi Kitano is a director of the Institute for Polymer-Water Interfaces (Toyama, Japan). He earned his Dr. Eng. in Kyoto University (1980). He was a full professor of University of Toyama from 1992 to 2016. His research interests are focused on the structure analyses of water in the vicinity of polymer materials, development and application of biocompatible polymers, and analyses of molecular recognition processes at the interfaces of water-polymer materials.   

Tetsuji YAMAOKA

Tetsuji YAMAOKA is a director of Department of Biomedical Engineering of National Cerebral and Cardiovascular Center Research Institute (Osaka Japan).   He earned his Dr. Eng. in Kyoto University (1993). He is a Fellow of Biomaterials Science and Engineering (FBSE) and Japanese Delegate of the International Union of Societies for Biomaterials Science and Engineering. His research interests are cardiovascular artificial organs, regenerative medicines, and molecular imaging.

 

Yoshiko Miura

Yoshiko Miura is a Professor at Kyusyu University. She received her B. Eng. Degree in 1995, M. Eng. Degree in 1997, and Dr. Eng. Degree in 2000 from the Kyoto University. She was appointed Assistant Professor at Nagoya University in 2001, Associate Professor at JAIST in 2005, and Professor at Kyushu University in 2010. Her research interests are biomaterial fabrication with glycopolymers and glyco-nanoparticles.

Inhalt

Preface 5
Contents 7
The Principle and Physical Chemistry of Soft Interface 9
1 The Principle and Physical Chemistry of Soft Interface 10
1.1 Colloid and Interface (Molecular Force, Colloid, Air/Water Interface) 10
1.1.1 Molecular Force 10
1.1.2 Colloid 12
1.1.3 Stability of Colloid 12
1.1.4 Surface Adsorption 16
1.2 Wettability and Molecular Science 19
1.2.1 Surface Tension 19
1.2.2 Wettability 21
1.3 Surfactants (Structure and Function, Emulsion) 23
1.3.1 Surfactants 23
1.3.2 Surfactant-Stabilized Soft Dispersed Systems 27
References 30
Design of Soft Interface (Synthesis and Processing) 33
2 Molecular Design of Soft Interface 34
2.1 Polymerization Method 34
2.2 Iniferter 36
2.3 Stable Free Radical Polymerization (NMP) 37
2.4 Atom Transfer Radical Polymerization (ATRP) 40
2.5 Reversible Addition-Fragmentation Chain Transfer (RAFT) Radical Polymerization 42
2.6 Organotellulium-Mediated Living Radical Polymerization (TERP) 46
2.7 Block Copolymers 48
2.8 Graft Copolymers 51
2.9 Hydrophobically Modified Polyelectrolytes (Random Copolymers) 53
2.10 Gels 54
References 55
3 Nano- and Micro-technology of Soft Interface 60
3.1 Supramolecular Formation 60
3.1.1 Supramolecular Formation with Biomacromolecules 60
3.1.2 Supramolecular Nanomaterials 61
3.1.3 Langmuir and Langmuir–Blodgett Membranes 63
3.1.4 Self-assembled Monolayer (SAM) 65
3.1.5 Alternate Layer-by-Layer Assembly (LBL) 66
3.1.6 Polymers with Special Structure 68
3.1.7 Hyperbranched Polymers 71
3.1.8 Polyrotaxane 72
3.2 Nano- and Microfabrication of Soft Interface 73
3.2.1 Intelligent Soft Interfaces for Biology 73
References 77
Characterization and Physical Properties of Soft Interface 80
4 Infrared and Raman Spectroscopy for Thin-Film Analysis 81
4.1 Infrared Spectroscopy 81
4.2 Raman Spectroscopy 86
References 88
5 Sum Frequency Generation (SFG) 90
5.1 Introduction 90
5.2 Principle 90
5.3 Peak Assignments [11] 92
5.4 Orientation of Functional Groups 93
5.4.1 PMMA/N2 Interface 94
5.4.2 PMMA/Water Interface 96
5.4.3 Water Structure at the PMMA Interface 99
5.5 Conclusions 100
References 100
6 Surface Analysis 103
6.1 X-Ray Photoelectron Spectroscopy (XPS) 103
6.1.1 Introduction 103
6.1.2 Surface Segregation in Polymer Blends [1] 104
6.1.3 Chain End Segregation in Polymer Blends [6] 108
6.1.4 Summary 109
6.2 Secondary Ion Mass Spectroscopy (SIMS) 109
6.2.1 Introduction 109
6.2.2 Surface Composition in an Isotopic Polymer Blend (SSIMS) [11] 110
6.2.3 Mobility Gradient Near Polymer Surfaces (DSIMS) [13] 111
6.2.4 Summary 115
References 115
7 Scattering and Reflection 117
7.1 Static and Dynamic Light Scattering (SLS, DLS) 117
7.2 Small-Angle X-Ray and Neutron Scattering (SAXS, SANS) 123
References 128
8 X-Ray and Neutron Reflectivity and Grazing Incidence X-Ray Diffraction 130
8.1 Background 130
8.2 Reflectivity 132
8.3 Example of Reflectivity from Thin Films 134
8.4 Grazing Incidence Wide-Angle X-Ray Diffraction 138
8.5 Conclusions and Perspective 138
References 140
9 Scanning Electron Microscopy 141
9.1 Introduction 141
9.2 Basic Components of SEM 142
9.3 Various Information Obtainable in SEM 142
9.4 A New Type of SEM—Atmospheric SEM 144
References 146
10 Transmission Electron Microscopy 147
10.1 Introduction 147
10.2 Basic Components of TEM 148
10.3 Various Modes in TEM Observations 150
10.4 An Example of Visualization of Soft Interface by TEM 152
References 153
11 Scanning Probe Microscopy (SPM) 154
11.1 Introduction 154
11.2 Scanning Tunneling Microscopy (STM) 155
11.3 Atomic Force Microscopy (AFM) 157
11.4 Other Scanning Probe Techniques 161
References 162
Application of Soft Interface 164
12 High-Performance Interface 165
12.1 Polymer Brush 165
12.2 Wettability and Antifouling 166
12.3 Adhesion 168
12.4 Friction and Lubrication 170
12.5 Conclusions 173
References 174
13 Bio- and Chemical Sensors and Role of Soft Interface 179
13.1 Bio- and Chemical Sensors and Soft Interfaces (Introduction) 179
13.2 Methodology of Sensing/Biosensing— Electrochemistry, QCM, SPR, and FET 183
13.2.1 Quartz Crystal Microbalance (QCM) 183
13.2.2 Surface Plasmon Resonance (SPR) Measurement 186
13.2.3 Electrochemistry 188
13.2.4 Field-Effect Transistors (FETs) 189
13.3 Biosensing by Various Methods 191
13.3.1 QCM Measurements 191
13.3.2 Surface Plasmon Resonance Measurements 191
13.3.3 Electrochemical Methods 193
13.3.4 Field-Effect Transistors (FETs) 194
References 195
14 Nonprotein-Fouling, Hemocompatible, and Biospecific Surfaces Generated with Phospholipid Polymers 197
14.1 General Background of Protein Adsorption 197
14.2 Design of Phosphorylcholine-Bearing Polymers 198
14.3 Mechanism of Nonprotein Fouling on MPC Polymer Surfaces 199
14.4 Hemocompatibility of MPC Polymers 200
14.5 Regulation of Specific Molecular Interactions on MPC Polymer Surfaces 202
14.5.1 Protein-Conjugated Surfaces 202
14.5.2 Protein-Imprinted Surfaces 203
14.5.3 Carbohydrate-Bearing Surfaces 204
14.6 Conclusion 205
References 205
15 Stem Cell Purification on a Cell-Compatible, Cell-Specific Biointerface 208
15.1 Introduction 208
15.2 Stem Cell Separation 210
15.3 Cell Rolling Mechanisms 212
15.4 Cell Separation on Ligand-Immobilized Column 212
15.5 Mesenchymal Stem Cells Separation 215
15.6 Conclusion 216
References 218

Produkt-Details

• Erscheint lt. Verlag: 9.5.2019
• Zusatzinfo: VIII, 222 p. 138 illus., 43 illus. in color.
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie ► Festkörperphysik
• Themenwelt: Technik ► Maschinenbau
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• Themenwelt: Wirtschaft
• Schlagworte: biomaterials • Functional polymer • Functional Soft Materials • Organic Thin Layer • Polymer brush • Polymer Surface Analysis • Soft Interface
• ISBN-10: 4-431-56877-8 / 4431568778
• ISBN-13: 978-4-431-56877-3 / 9784431568773