Rhodium Catalysis in Organic Synthesis (eBook)

Methods and Reactions

Ken Tanaka (Herausgeber)

eBook Download: PDF

2018 | 1. Auflage
688 Seiten
Wiley-VCH Verlag GmbH & Co. KGaA
978-3-527-81187-8 (ISBN)

Infos

An essential reference to the highly effective reactions applied to modern organic synthesis

Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic Synthesis explores the most recent progress and new developments in the field of catalytic cyclization reactions using rhodium(I) complexes and catalytic carbon-hydrogen bond activation reactions using rhodium(II) and rhodium(III) complexes.

Edited by a noted expert in the field with contributions from a panel of leading international scientists, Rhodium Catalysis in Organic Synthesis presents the essential information in one comprehensive volume. Designed to be an accessible resource, the book is arranged by different reaction types. All the chapters provide insight into each transformation and include information on the history, selectivity, scope, mechanism, and application. In addition, the chapters offer a summary and outlook of each transformation. This important resource:

-Offers a comprehensive review of how rhodium complexes catalyze a variety of highly useful reactions for organic synthesis (e.g. coupling reactions, CH-bond functionalization, hydroformylation, cyclization reactions and others)
-Includes information on the most recent developments that contain a range of new, efficient, elegant, reliable and useful reactions
-Presents a volume edited by one of the international leading scientists working in the field today
-Contains the information that can be applied by researchers in academia and also professionals in pharmaceutical, agrochemical and fine chemical companies

Written for academics and synthetic chemists working with organometallics, Rhodium Catalysis in Organic Synthesis contains the most recent information available on the developments and applications in the field of catalytic cyclization reactions using rhodium complexes.

Autor

Ken Tanaka is a Professor of Applied Chemistry in the Graduate School of Science and Engineering at the Tokyo Institute of Technology. Since the start of his academic career in 2003, he has published over 165 scientific papers and one book. His research focuses on organometallic chemistry directed toward organic synthesis.

Inhalt

RHODIUM(I) CATALYSIS
Rhodium(I)-Catalyzed Asymmetric Hydrogenation
Rhodium(I)-Catalyzed Hydroboration and Diborylation
Rhodium(I)-Catalyzed Hydroformylation and Hydroamination
Rhodium(I)-Catalyzed Hydroacylation
Rhodium(I)-Catalyzed (Asymmetric) Addition of Organometallic Reagents to Unsaturated Compounds
Rhodium(I)-Catalyzed Allylation with Alkynes and Allenes
Rhodium(I)-Catalyzed Reductive Carbon-Carbon Bond Formation
Rhodium(I)-Catalyzed [2+2+1] and [4+1] Cycloadditions
Rhodium(I)-Catalyzed [2+2+2] and [4+2] Cycloadditions
Rhodium(I)-Catalyzed Annulation Involving Vinylcyclopropanes
Rhodium(I)-Catalyzed Reactions via Carbon-Hydrogen Bond Cleavage
Rhodium(I)-Catalyzed Reactions via Carbon?Carbon Bond Cleavage

RHODIUM(II) CATALYSIS
Rhodium(II) Tetracarboxylate-Catalyzed Enantioselective C?H Functionalization Reactions
Rhodium(II)-Catalyzed Nitrogen-Atom Transfer for Oxidation of Aliphatic C?H Bonds
Rhodium(II)-Catalyzed Cyclopropanation
Reactions of alpha-Imino Rhodium(II) Carbene Complexes Generated from N-Sulfonyl-1,2,3-Triazoles
Rhodium(II)-Catalyzed 1,3- and 1,5-Dipolar Cycloaddition

RHODIUM(III) CATALYSIS
Rhodium(III)-Catalyzed Annulative Carbon-Hydrogen Bond Functionalization
Rhodium(III)-Catalyzed Non-Annulative Carbon-Hydrogen Bond Functionalization
Sterically and Electronically Tuned Cp Ligands for Rhodium(III)-Catalyzed Carbon-Hydrogen Bond Functionalization
Chiral Cp Ligands for Rhodium(III)-Catalyzed Asymmetric Carbon-Hydrogen Bond Functionalization

Produkt-Details

• Erscheint lt. Verlag: 28.12.2018
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Schlagworte: Chemie • Chemistry • Homogene Katalyse • Homogeneous catalysis • Methods - Synthesis & Techniques • Organische Chemie / Methoden, Synthesen, Verfahren • Organische Synthese • Pharmaceutical & Medicinal Chemistry • Pharmazeutische u. Medizinische Chemie • Rhodium
• ISBN-10: 3-527-81187-7 / 3527811877
• ISBN-13: 978-3-527-81187-8 / 9783527811878