Advances in Magnetic Resonance (eBook)

Volume 1

John S. Waugh (Herausgeber)

eBook Download: PDF

2013 | 1. Auflage
426 Seiten
Elsevier Science (Verlag)
978-1-4832-8150-6 (ISBN)

Infos

Advances in Magnetic Resonance, Volume 1, discusses developments in various areas of magnetic resonance. The subject matter ranges from original theoretical contributions through syntheses of points of view toward series of phenomena to critical and painstaking tabulations of experimental data. The book contains six chapters and begins with a discussion of the theory of relaxation processes. This is followed by separate chapters on the development of magnetic resonance techniques for studying rate processes in chemistry and the application of these techniques to various problems; the geometrical and electronic structures of paramagnetic molecules and complex ions; and various theoretical formulations of spin-spin coupling. Subsequent chapters deal with geminal and vicinal proton-proton coupling constants from values reported in the literature; and electron spin resonance of radical ions. This serial publication was conceived with the insiders as well as the interested outsiders in mind. The editor hopes that readers who consult this book for a particular article will in some measure profit by being exposed to some of the other contributions.

Inhalt

Front Cover 
1 
Advances in Magnetic Resonance 4
Copyright Page 
5 
Table of Contents 
10 
Contributors 6
Preface 8
Tentative Contents of Future Volumes 12
Chapter 1. The Theory of Relaxation Processes 14
I. Introduction 14
II. Random Perturbation 19
III. Dynamical Interaction with a Thermal Bath 28
IV. Time-Dependent Hamiltonian 34
V. Applications 37
Appendix A 43
Appendix B 43
ACKNOWLEDGMENTS 45
Chapter 2. Chemical Rate Processes and Magnetic Resonance 46
I. Introduction 46
II. Line Shapes and the Motion of Spins 49
III. Slow Passage Line Shapes and the Determination of Reaction Rates 77
IV. Transient Methods for the Measurement of Rates 101
V. Conclusion 114
Chapter 3. Nuclear Magnetic Resonance of Paramagnetic Molecules 116
I. Introduction 116
II. Applications 129
Note Added in Proof 161
Chapter 4. Theory of Nuclear Spin-Spin Coupling 162
I. Introduction 162
II. Experimental Basis 163
III. Physical Basis-Spin-Spin Coupling Hamiltonian 164
IV. Coupling between Directly Bonded Nuclei 170
V. Molecular Wave Mechanical Formulations 178
VI. Spin-Spin Coupling between Nondirectly Bonded Nuclei 187
VII. General Conclusions 205
Chapter 5. Geminal and Vicinal Proton-Proton Coupling Constants in Organic Compounds 208
I. Introduction 208
II. Geminal Coupling Constants 209
III. Vicinal Coupling Constants across Formal Single Bonds 214
IV. Couplings in Ethylenes and Substituted Ethylenes 220
V. Benzene and Substituted Benzenes 221
VI. Heterocycles 222
Tables 224
References 322
Chapter 6. Electron Spin Resonance of Radical Ions 330
I. Introduction 330
II. Survey of Recent Developments 330
III. Table of Splitting Constants of Hydrocarbon Radical Ions in Solution 334
References to Table 407
Author Index 410
Subject Index 425

Produkt-Details

• Erscheint lt. Verlag: 22.10.2013
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie ► Elektrodynamik
• Themenwelt: Technik
• ISBN-10: 1-4832-8150-7 / 1483281507
• ISBN-13: 978-1-4832-8150-6 / 9781483281506