Zeolite Chemistry and Catalysis (eBook)

P.A. Jacobs, N.I. Jaeger, L. Kubelkova, B. Wichterlova (Herausgeber)

eBook Download: PDF

1991 | 1. Auflage
513 Seiten
Elsevier Science (Verlag)
978-0-08-088722-7 (ISBN)

Infos

These proceedings reflect recent developments in the field of zeolite chemistry and catalysis with an emphasis on the role of a modifying component on the properties of the molecular sieve material. The plenary lectures and contributed papers concentrate on the problem of isomorphous substitution in a zeolitic framework, on the occlusion and the structure of metal, metal oxide, and metal sulphide clusters and complexes in the intracrystalline void volume of molecular sieves and zeolites as well as in the interlaminar space of layered compounds.

Catalytic applications are discussed, not only in regard to traditional hydrocarbon transformation, but also in such areas as: reduction of SO2, decomposition of NO, reactions of sulphur containing compounds and conversion of CO, CO2 to hydrocarbons or of alcohols to oxygenated products.

Because the book provides valuable data and information on new achievements in the zeolite material science and application, it will be of considerable interest to all research groups involved in zeolite science.

Inhalt

Front Cover 1
Zeolite Chemistry and Catalysis 4
Copyright Page 5
Contents 6
Preface 12
Acknowledgements 13
Organizing and Scientific Committee 14
Financial Support 15
Chapter 1. Hydrocarbon Transformations over Analogues and Derivatives of Zeolite Y 16
Chapter 2. Isomorphous Substitution in Zeolitic Frameworks: Procedures and Characterization 40
Chapter 3. Introduction of Cations into Zeolites by Solid-state Reaction 58
Chapter 4. Zeolite-hosted Metals and Semiconductors as Advanced Materials 80
Chapter 5. Isomorphous Substitution in Zeolites: a Route for the Preparation of Novel Catalysts 94
Chapter 6. Zeolite Synthesis with Metal Chelate Complexes 108
Chapter 7. Synthesis of Ferrous Cyanide Complexes inside Zeolite Y 116
Chapter 8. Genesis of Gallosilicates with ZSM-5 Structure. Insertion of Ga and Zeolitic Properties at Various Steps of Crystallization 124
Chapter 9. Studies on the Phosphorus Substituted Zeolites Prepared by Secondary Synthesis 134
Chapter 10. Synthesis of Zeolite Beta in Boron-Aluminium Media 142
Chapter 11. On the Possibility of Generation of Brønsted Acidity by Silicon Incorporation in Very Large Pore Alp04 Molecular Sieves 150
Chapter 12. Crystallization of Porous Alurninophosphates and Metal Substitutions 160
Chapter 13. Factors Affecting the Crystallization of Zeolite ZSM-48 172
Chapter 14. Synthesis and Characterization of Cr-modified Silicalite-1 180
Chapter 15. Synthesis, Characterization and Catalytic Activity of V-ZSM-5 Zeolites 188
Chapter 16. A Study of Acid Sites in Substituted AlPO-5 196
Chapter 17. Structure and Photocorrosion of NaX Hosted Q-Size Metal Sulfide Particles 204
Chapter 18. Faujasite-Hosted Methylene Blue: Synthesis, Optical Spectra and Spectral Hole Burning 214
Chapter 19. Preparation and Characterization of Zinc-ZSM-5 Catalyst 222
Chapter 20. The Formation of Well Defined Surface Carbonyls of Ru and Ir with Highly Dealurninated Zeolite Y as Matrix 230
Chapter 21. A Comparative Study of State and Reactivity of Copper Ions Embedded in Various Molecular Sieve Materials 238
Chapter 22. Acidity, Redox Behaviour and Stability of CoAPO Molecular Sieves of Structure Types 5, 11, 34 and 16 246
Chapter 23. State of Iron and Catalytic Properties of Akali- Metal-Exchanged Ferrisilicate Zeolite Molecular Sieves 256
Chapter 24. Framework and Extraframework Ti in Titanium- Silicalite: Investigation by Means of Physical Methods 266
Chapter 25. Studies on the State of Copper and the Formation of Its Oxidic and Metallic Phases in Zeolite CuNaY 274
Chapter 26. ESCA Study of Incorporation of Copper into Y Zeolite 284
Chapter 27. Preparation of Ga-Doped Zeolite Catalysts via Hydrogen Induced Solid-state Interaction between Ga 2o3 and HZSM-5 Zeolite 292
Chapter 28. Comparison of Hydrosulfurization Zeolite Catalysts Prepared in Different Ways 302
Chapter 29. Effect of the Introduction of Ni(II) on the Catalytic Properties of SAPO-5 Molecular Sieves 310
Chapter 30. Study of Broensted and Lewis Acid Sites in Phosphates, Silicates and Silica Gels with Molecular Sieve Properties 318
Chapter 31. Influence of Framework Phosphorus on the Acidic Properties of Faujasite Type Zeolite 328
Chapter 32. Zn-Doped HZSM5 Catalysts for Propane Aromatization 336
Chapter 33. Sulfided Ni-Mo-Y Zeolites as Catalysts for Hydrogenation and Hydrodesulfurization Reactions 346
Chapter 34. Reduction of SO on Molybdenum Loaded Y Zeolite 354
Chapter 35. Contribution of Metal Cations to the Para-Selectivity of Small Crystals of H-ZSM-5 Zeolite in Toluene Alkylation with Ethylene 362
Chapter 36. NO Decomposition on Cu-Incorporated A-Zeolites under the Reaction Condition of Excess Oxygen with a Small Amount of Hydrocarbons 370
Chapter 37. A Comparison of the Catalytic Properties of SAPO-37 and HY Zeolite in the Cracking of n-Heptane and 2,2,4 -Trimethylpentane 380
Chapter 38. Cracking of Light Alkanes over MeAPO-5 Molecular Sieves 388
Chapter 39. Promoting Effect of Pt Supported on Galliumsilicate in n-C4HI0 Aromatization 396
Chapter 40. Conversion of Ally1 Alcohol to Oxygenated Products over Zeolite Catalysts 404
Chapter 41. Cation Exchange Influence on the Activity of Zeolites in Reactions between Alcohols and Hydrogen Sulphide 412
Chapter 42. Possible Intermediates during C3H8 aromatization over Ga-HZSM-5 Catalyst 420
Chapter 43. Dehydrocyclodimerization of Short Chain Alkanes on Ga/ZSM-5 and Ga/beta Zeolites 424
Chapter 44. Bifunctional Cobalt-ZSM-5 Catalyst for the Synthesis of Hydrocarbons from the Products of Biomass Gasification 432
Chapter 45. Shape Selective Reforming: Possible Reaction Pathways on Platinum-Containing Erionite/Alumina Catalysts 440
Chapter 46. Framework Ordering in Aluminophosphate Molecular Sieves Studied by 27A1 Double Rotation NMR 450
Chapter 47. A Computer Analysis of ESR Powder Spectra of Silver and Sodium Clusters in Molecular Sieves 458
Chapter 48. Magic-Angle-Spinning Nuclear Magnetic Resonance and Infrared Studies on Modified Zeolites 468
Chapter 49. 129Xe NMR Study of Intra- and Inter-Crystallite Diffusion of Cations in Faujasite Zeolites 476
Chapter 50. Intracrystalline Diffusion of Benzene in Ga-Silicate 484
Chapter 51. Intracrystalline Diffusivities of HZSM-5 Zeolites 492
Chapter 52. New Porous Materials from Layered Compounds 500
Author Index 514
Subject Index 520
Studies in Surface Science and Catalysis 526

Produkt-Details

• Erscheint lt. Verlag: 17.9.1991
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Technische Chemie
• Themenwelt: Naturwissenschaften ► Geowissenschaften ► Mineralogie / Paläontologie
• Themenwelt: Technik ► Umwelttechnik / Biotechnologie
• ISBN-10: 0-08-088722-8 / 0080887228
• ISBN-13: 978-0-08-088722-7 / 9780080887227